引用本文:秦艳红,秦玮,杜嵩山,蒋自强等.南京某典型化工园区春季VOCs污染特征和臭氧生成潜势分析[J].环境监控与预警,2021,13(6):37-42
QIN Yan-hong, QIN Wei, DU Song-shan, JIANG Zi-qiang,et al.Characterization of Volatile Organic Compounds and Ozone Formation Potentials in a Chemical Industrial Park of Nanjing During Spring[J].Environmental Monitoring and Forewarning,2021,13(6):37-42
【打印本页】   【HTML】   【下载PDF全文】   查看/发表评论  【EndNote】   【RefMan】   【BibTex】
←前一篇|后一篇→ 过刊浏览    高级检索
本文已被:浏览 1811次   下载 523 本文二维码信息
码上扫一扫!
分享到: 微信 更多
南京某典型化工园区春季VOCs污染特征和臭氧生成潜势分析
秦艳红,秦玮,杜嵩山,蒋自强等1,2
1.江苏省环境监测中心,江苏 南京 210019;2.江苏省苏力环境科技有限责任公司,江苏 南京 210019
摘要:
利用2020年3月28日—5月3日南京某典型化工园区挥发性有机物(VOCs)离线监测数据,分析了园区内VOCs污染特征及臭氧生成潜势(OFP)。结果表明,春季园区φ(VOCs)范围为22.3×10-9 ~892.6×10-9,82.1%频率的φ(VOCs)<100×10-9;VOCs组分占比表现为:烷烃>含氧挥发性有机物(OVOCs)>烯烃>卤代烃>芳香烃>炔烃>有机硫。高体积分数VOCs中烷烃和烯烃占比高于低体积分数VOCs,受园区内部储罐存储、运输、转运等过程产生的油气挥发及石油化工原料、合成材料的生产影响显著。不同时刻φ(VOCs)表现为夜间最高、早晨其次、下午最低的变化特征,这与园区内部VOCs排放累积、大气边界层抬升和大气光化学反应等因素有关。OFP值范围为166.2~6 920.9 ,μg/m3,56.0%频率的OFP<500。
关键词:  化工园区  挥发性有机物  臭氧生成潜势  污染特征  南京市
DOI:
分类号:X51
基金项目:国家重点研发计划基金资助项目(2018YFC02090800);江苏省PM2.5与臭氧协同控制专项重大基金资助项目(2019023);江苏省环境监测科研基金资助项目(1918,1917)
Characterization of Volatile Organic Compounds and Ozone Formation Potentials in a Chemical Industrial Park of Nanjing During Spring
QIN Yan-hong, QIN Wei, DU Song-shan, JIANG Zi-qiang,et al1,2
1.Jiangsu Provincial Environmental Monitoring Center, Nanjing,Jiangsu 210019,China;2.Jiangsu Suli Environmental Science and Technology Co. Ltd., Nanjing, Jiangsu 210019, China
Abstract:
Using the offline monitoring data of VOCs in a typical chemical industry park in Nanjing from March 28 to May 3, 2020, analyzed and studied the characteristics of VOCs pollution and its ozone formation potentials. The results showed that the concentration of VOCs in the Nanjing Chemical Industry Park in spring ranged from 22.3×10-9 to 892.6 ×10-9, and the VOCs concentration in 82.1% is less than 100×10-9. The proportion of VOCs components was expressed as alkane>OVOCs>olefin>halogenated hydrocarbons>aromatic hydrocarbons>alkynes>organic sulfur. Alkanes and olefins in high concentration VOCs accounted for an increase in low-concentration VOCs, which was significantly affected by the volatilization process of oil and gas involved in the storage, transportation, and transfer processes in the chemical parks internal storage tanks and the production of petrochemical raw materials and synthetic materials. The concentration of VOCs at different times was characterized by the highest concentration at night, the second in the morning, and the lowest in the afternoon, which was related to the integrated factors of the accumulation of VOCs emissions in the park, the uplift of the atmospheric boundary layer and the atmospheric photochemical reaction. The concentration of OFP was 166.2~6 920.9 μg/m3, and the concentration of OFP is less than 500.
Key words:  Chemical industry park  VOCs  Ozone formation potentials  Pollution characteristics  Nanjing city